The Basic Theorem of Temperature-Dependent Processes

نویسندگان

چکیده

The basic theorem of isokinetic relationships is formulated as “if there exists a linear correlation “structure?properties” at two temperatures, the point their intersection will be common for same other until Arrhenius law violated”. valid in various regions thermally activated processes, which only one parameter changes. A detailed examination consequences this showed that it easy to formulate number empirical regularities known “kinetic compensation effect”, well-known formula Meyer–Neldel rule, or so-called concept “multi-excitation entropy”. In series similar we examined effect different variable parameters process on free energy activation, and discuss possible applications.

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ژورنال

عنوان ژورنال: Thermo

سال: 2021

ISSN: ['2673-7264']

DOI: https://doi.org/10.3390/thermo1010004